کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1334058 | 979136 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Directing the structures of silver-antimony sulphides: A new topological variant of the [Ag5Sb3S8]2− double layer
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Directing the structures of silver-antimony sulphides: A new topological variant of the [Ag5Sb3S8]2− double layer Directing the structures of silver-antimony sulphides: A new topological variant of the [Ag5Sb3S8]2− double layer](/preview/png/1334058.png)
چکیده انگلیسی
A new silver–antimony sulphide, [C6H20N4][Ag5Sb3S8], has been synthesised solvothermally in the presence of triethylenetetramine and characterised by single-crystal X-ray diffraction, thermogravimetry and elemental analysis. The compound crystallises in the space group P21/m (a=6.2778(7)a=6.2778(7), b=15.8175(16)b=15.8175(16) and c=12.4617(15)Å and β=104.561(5)°β=104.561(5)°) and adopts a structure in which honeycomb-like sheets of fused six-membered silver–antimony-sulphide rings are linked through Ag–S bonds to form double layers. The idealised structure can be considered to be derived from that of antifluorite and represents a second structure type for the [Ag5Sb3S8]2− double layer.
.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Solid State Chemistry - Volume 178, Issue 11, November 2005, Pages 3414–3419
Journal: Journal of Solid State Chemistry - Volume 178, Issue 11, November 2005, Pages 3414–3419
نویسندگان
Anthony V. Powell, Jürgen Thun, Ann M. Chippindale,