کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1334121 | 979147 | 2005 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Template-controlled reactivity: Following nature's way to design and construct metal-organic polyhedra and polygons Template-controlled reactivity: Following nature's way to design and construct metal-organic polyhedra and polygons](/preview/png/1334121.png)
We show how a template-controlled reaction performed in the organic solid state can be used to construct a molecule that functions as an organic building unit of both a metal-organic polyhedron and polygon. The template is a small organic molecule that organizes two olefins via hydrogen bonds for a [2+2] photodimerization. The process of utilizing a molecule to build a molecule that is subsequently used for self-assembly is inspired by the general two-step process of template-directed synthesis and self-assembly of Nature that is used to construct large, functional self-assembled structures.
A metal-organic polygon and polyhedron are obtained from a molecule constructed in the organic solid state using a linear template.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 178, Issue 8, August 2005, Pages 2409–2413