کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1386004 | 982467 | 2009 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
An effective method to prepare sucrose polymers by Thiol-Ene photopolymerization
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
A facile method to obtain novel sucrose polymers is reported. These polymers were obtained by means of the Thiol-Ene photopolymerization technique. The sucrose was functionalized with allyl groups by etherification with allyl bromide and then photopolymerized by the step-growth mechanism with multifunctional thiols. The kinetics of photopolymerization were determined by optical pyrometry and Real-Time FT-IR. It was found that this photocurable system was highly reactive obtaining solid crosslinked polymers that displayed high uniformity in the crosslink density. A Tg of 58 °C was determined by means of DMA for the polymer derived from A2S and PETKMP. The prepared polymers displayed thermal stability up to 230 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 78, Issue 2, 5 September 2009, Pages 282–286
Journal: Carbohydrate Polymers - Volume 78, Issue 2, 5 September 2009, Pages 282–286
نویسندگان
Ricardo Acosta Ortiz, Aida E. Garcia Valdéz, Marty Georgina Martinez Aguilar, Maria Lydia Berlanga Duarte,