Preparation and properties of the aldohexofuranose pentaacetates

The preparation of one isomer of each of the 16 enantiomeric pairs of the aldohexofuranose pentaacetates is described together with 1H and 13C NMR data. Eight of the isomers have been obtained crystalline. Equilibrium values for the anomeric pairs have been determined.

Sixteen aldohexofuranose pentaacetates have been prepared. 1H and 13C NMR data are given together with equilibrium values for the anomeric pairs.Figure optionsDownload as PowerPoint slide