کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1389584 982897 2005 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of methyl 4′-O-methyl-13C12-β-d-cellobioside from 13C6-d-glucose. Part 1: Reaction optimization and synthesis
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis of methyl 4′-O-methyl-13C12-β-d-cellobioside from 13C6-d-glucose. Part 1: Reaction optimization and synthesis
چکیده انگلیسی

A high yielding synthetic route for methyl 4′-O-methyl-β-d-cellobioside starting from d-glucose was established. The reaction conditions optimized with nonlabeled materials were used for the synthesis of methyl 4′-O-methyl-13C12-β-d-cellobioside, a compound having more than 99% 13C enrichment at each of the twelve pyranose carbon atoms. The labeled compound is required to study the hydrogen bond network of cellodextrins and cellulose by CPMAS NMR experiments.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 340, Issue 15, 31 October 2005, Pages 2428–2435
نویسندگان
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