کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1389850 | 982928 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solid-state hydrolysis of cellulose and methyl α- and β-d-glucopyranosides in presence of magnesium chloride
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
Solid-state hydrolysis proceeded with cellulose and methyl α- and β-d-glucopyranosides in the presence of hydrated magnesium chloride. This reaction was effective even at >100 °C since the hydrated water, which is held by MgCl2 up to >200 °C, is utilized as a nucleophile. Excess water made this reaction ineffective due to the competition between water and sugar oxygen atoms in coordinating with Mg2+, a Lewis acid. Consequently, this hydrolysis reaction is characteristic of solid-state reactions.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 342, Issue 10, 23 July 2007, Pages 1373–1377
Journal: Carbohydrate Research - Volume 342, Issue 10, 23 July 2007, Pages 1373–1377
نویسندگان
Naoki Shimada, Haruo Kawamoto, Shiro Saka,