کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1390521 983097 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel preparation of methyl-β-cyclodextrin from dimethyl carbonate and β-cyclodextrin
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
A novel preparation of methyl-β-cyclodextrin from dimethyl carbonate and β-cyclodextrin
چکیده انگلیسی

A novel green synthesis process about methyl-β-cyclodextrin has been investigated through the reaction between β-cyclodextrin and dimethyl carbonate by anhydrous potassium carbonate as catalyst in DMF. The influence of experimental factors including the molar ratio of dimethyl carbonate to β-cyclodextrin, reaction temperature, and reaction time on the average degree of substitution of methyl-β-cyclodextrin was studied. The results show that the average degree of substitution of methyl-β-cyclodextrin can be dependent on the reaction temperature and the molar ratio of raw material primarily. The structures of methyl-β-cyclodextrin were characterized by TLC, IR, MS, 1H NMR, and 13C NMR.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 346, Issue 3, 15 February 2011, Pages 389–392
نویسندگان
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