کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1394883 | 1501364 | 2015 | 13 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Blending poly(butylene succinate) with poly(lactic acid): Ductility and phase inversion effects Blending poly(butylene succinate) with poly(lactic acid): Ductility and phase inversion effects](/preview/png/1394883.png)
• PBS is not miscible with PLA to any substantial extent, but compatibility is achieved at low addition levels (20 wt%).
• Elongation-to-break increased to over 250% with as little as 10 wt% of PBS added.
• PLA and PBS formed a co-continuous phase in the composition range of 8–42 wt% of PBS.
• The theoretical value of the phase inversion point calculated from viscosity measurements was 8.4 wt%.
Synergistic effects of blending two bio-based, bio-degradable polymers, poly(butylene succinate) (PBS) and poly(lactic acid) (PLA) are investigated. A series of melt-blended compounds were prepared at PBS/PLA weight ratios of 0/100, 10/90, 20/80, 40/60, 60/40, 80/20 and 100/0. Thermal properties, crystallinity, melt viscosities, mechanical properties and phase morphology were studied. There was found to be a dramatic improvement in ductility, over 250% elongation-to-break, with as little as 10 wt% of PBS added. This was shown to be due to a co-continuous phase morphology, which was determined by the relative viscosities of the components.
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Journal: European Polymer Journal - Volume 71, October 2015, Pages 534–546