کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1396654 | 984188 | 2007 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and polymerization of active ester monomers based on 4-vinylbenzoic acid
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and polymerization of active ester monomers based on 4-vinylbenzoic acid Synthesis and polymerization of active ester monomers based on 4-vinylbenzoic acid](/preview/png/1396654.png)
چکیده انگلیسی
Nine active ester monomers based on 4-vinylbenzoic acid have been synthesized. Under free radical polymerization conditions these monomers could successfully be polymerized yielding reactive polymers with molecular weights of around Mn = 20.000–50.000 g/mol and molecular weight distributions Mw/Mn of around or below 2 in good yields. Polymer analogous reactions with amines have been investigated by time-resolved FT-IR spectroscopy and it was found that especially poly(pentafluorophenyl 4-vinylbenzoate) featured a significant reactivity, such that polymer analogous reactions proceeded quantitatively with amines within less than 5 min at 0 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: European Polymer Journal - Volume 43, Issue 7, July 2007, Pages 2901–2912
Journal: European Polymer Journal - Volume 43, Issue 7, July 2007, Pages 2901–2912
نویسندگان
Katja Nilles, Patrick Theato,