Sulphur-containing polymers: Synthesis and thermal properties of novel polyesters based on dithiotriethylene glycol

Poly(dithiotriethylene terephthalate) (PSSTET), poly(dithiotriethylene adipate) (PSSTEA), poly(triethylene terephthalate) (PTET) and poly(triethylene adipate) (PTEA), these two last for comparison, were synthesized and characterized in terms of chemical structure and molecular weight. The thermal behaviour was examined by thermogravimetric analysis and differential scanning calorimetry. All the polymers showed a good thermal stability, even though lower for the sulphur-containing polyesters. At room temperature they appeared as semicrystalline materials, except PTEA, which was an oil; the effect of substitution of ether oxygen atoms with sulphur ones was found to be a lowering in the Tg value, an increment of the melting temperature and an increase of the crystallization rate. The results were explained as due to the presence of flexible C–S–C bonds in the polymeric chain. Lastly, the absence of a rigid-amorphous phase was evidenced in PSSTET and PTET.