کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1398215 | 984346 | 2013 | 8 صفحه PDF | دانلود رایگان |

To improve the performance of temperature-sensitive poly(N-isopropylacrylamide) (PNIPAM) hydrogels, graphene oxide (GO) was selected as a nano strengthening agent to prepare nanocomposite hydrogels. For fulfilling this purpose, in situ polymerization was carried out in colloid solution of graphene oxide, where N-isopropylacrylamide as temperature-sensitive monomer and N,N′-methylene bisacrylamide as crosslinker was initiated utilizing potassium persulfate and sodium sulfite as redox initiators. Infrared spectroscopy and transmission electron microscope was employed to characterize the structure of GO and its dispersibility in water respectively. The internal network structure of nanocomposite hydrogels was investigated by scanning electron microscope (SEM). The temperature-sensitivity, swelling and deswelling properties and mechanical performance of the as-prepared nanocomposite hydrogels was investigated preliminarily. Experimental results show that the nanocomposite hydrogels prepared not only possess good temperature-sensitivity but improved swelling capabilities. The volume-phase transition temperatures of most composite hydrogels are shifted to higher temperature than PNIPAM hydrogels. Furthermore, addition of appropriate amount of GO can dramatically enhance the mechanical performance of PNIPAM hydrogels. The compressive strength of nanocomposite hydrogels reaches a maximum of 216 kPa when the weight ratio of GO to NIPAM is ∼5%, which is 4 times larger than that of PNIPAM hydrogels (54 kPa). The advantageous performance of nanocomposite hydrogels over PNIPAM hydrogels is very beneficial for future applications.
The internal network structure of the prepared hydrogels was investigated by scanning electronic microscope. The result suggests that incorporation of graphene oxide has significant influence on the internal network structure of the hydrogels. The network density increases and the pore sizes decreases respectively with the increase of GO content. The internal network structural feature has close relation to the mechanical behavior of hydrogels.Figure optionsDownload as PowerPoint slideHighlights
► Poly(N-isopropylacrylamide)/graphene oxide nanocomposite hydrogels were prepared.
► Incorporating GO influences the network structure of the composite hydrogels largely.
► The prepared hydrogels show good thermo-sensitivity and enhanced swelling capability.
► Moderate addition of GO can improve the hydrogels’ mechanical performance obviously.
Journal: European Polymer Journal - Volume 49, Issue 2, February 2013, Pages 389–396