On the polymerisation of the epoxidised biodiesel: The importance of the epoxy rings position, the process and the products

Polyesters were prepared using epoxidised methyl esters of oleic acid (EPOAME) and epoxidised biodiesel (mixture of methyl esters) from sunflower oil (EPSOME) and linseed oil (EPLOME) with cis-1,2-cyclohexanedicarboxylic anhydride and triethylamine. The kinetic of partial processes involved in the polymerisation were elucidated and related to epoxy rings position in the fatty acid chain. The activation energies (Ea) for the epoxy ring opening by the catalyst are 298, 216 and 136 kJ/mol for EPOAME, EPSOME and EPLOME respectively. The reactions of the epoxy rings in the positions C9–C10, C12–C13 and C15–C16 with anhydride require average activation energies of 116, 32 and 22 kJ/mol, respectively. The compensation effect between activation energy and pre-exponential factor is observed. The polymerisation enthalpy, molecular weight, glass transition temperature and electrical properties were determined. The polyesters studied show promising properties for use in various technological applications.

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► The viability to produce polyesters from epoxidised biodiesel.
► The position and the reactivity of epoxy rings.
► Kinetic of epoxy rings in the positions 9–10, 12–13, 15–16 in epoxidised biodiesel.