کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1400353 1501362 2015 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Transition from shish-kebab to fibrillar crystals during ultra-high hot stretching of ultra-high molecular weight polyethylene fibers: In situ small and wide angle X-ray scattering studies
ترجمه فارسی عنوان
انتقال از شیش کباب به کریستال های فیبردار در طول کشش فوق العاده بالا از الیاف پلی اتیلن با وزن مولکولی فوق العاده بالا: مطالعات پراکندگی اشعه ایکس در اندازه کوچک و گسترده
کلمات کلیدی
فیبر پلی اتیلن با وزن مولکولی فوق العاده بالا، شیشلیک، کریستال فیبریل، اندازه گیری در محل، پراکندگی اشعه ایکس کوچک و گسترده زاویه
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی


• UHMWPE pre-stretched fibers were examined by in situ SAXS/WAXD during the ultra-high stretching process.
• We reported the transition from shish-kebab to fibrillar morphology crystals of UHMWPE fibers.
• There still exist chain conformation defects even in the majorly fibrillar morphology crystals.

The ultra-high hot stretching was conducted on four-times pre-stretched ultra-high molecular weight polyethylene (UHMWPE) fibers to the ratio of about 508% to achieve the total ultra-high stretching ratio of about 2000%. In situ small and wide-angle X-ray scattering (SAXS/WAXS) measurements using synchrotron radiation and Raman spectroscopy were applied to study the structural evolutions of ultra-high stretched fibers. SAXS images revealed the transition from shish-kebab to fibrillar crystals, which is believed to involve with the increasing trans-configuration ratio of C–C backbone. WAXS results demonstrate the further stretching could still be applied to the fibers to acquire the complete extended-chain crystals.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: European Polymer Journal - Volume 73, December 2015, Pages 127–136
نویسندگان
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