کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1401033 | 984670 | 2008 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
endo-Selective (3+2) cycloaddition polymerizations of nitrone monomers with olefins utilising high pressure conditions
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: endo-Selective (3+2) cycloaddition polymerizations of nitrone monomers with olefins utilising high pressure conditions endo-Selective (3+2) cycloaddition polymerizations of nitrone monomers with olefins utilising high pressure conditions](/preview/png/1401033.png)
چکیده انگلیسی
A high pressure mediated (3+2) cycloaddition polymerization strategy has been employed to afford linear poly(isoxazolidine) architectures. Under these high pressure conditions this cycloaddition process was found to afford primarily endo-heterocycles which when translated to the polymerization should ultimately affect the tacticity and resultant properties of the polymer. The stereoselectivity occurred as a result of a lower volume of activation for the endo-transition state and the application of a 'type-I' regime (HOMODipole-LUMODipolarophile) cycloaddition process that features secondary orbital interactions within the extended molecular orbitals. A variety of linker segments were employed in an attempt to affect the physical properties of the polymeric cycloadducts such as Tg and solubility in order to tailor these materials for use in coating applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: European Polymer Journal - Volume 44, Issue 6, June 2008, Pages 1881-1890
Journal: European Polymer Journal - Volume 44, Issue 6, June 2008, Pages 1881-1890
نویسندگان
Glenn W. Goodall, Kevin Cosstick, Simon C. Richards, Wayne Hayes,