Synthesis and properties of poly(bisphenol A acryloxyethyl phosphate) as a UV curable flame retardant oligomer

Poly(bisphenol A acryloxyethyl phosphate) (BPAAEP) being used for UV curable flame retardant coatings and adhesives, was synthesized from phosphorus oxychloride, hydroxylethyl acrylate and bisphenol A as raw materials, and characterized using 13C NMR, 31P NMR, FTIR, MS and GPC measurements. A series of formulations with different ratios of BPAAEP to urethane acrylate, EB220, were prepared to obtain flame retardant resins. The flame retardancy of the UV cured films was investigated by the limiting oxygen index (LOI). A synergistic effect between phosphorus and nitrogen was observed when 1.5 wt% phosphorus was presented in the resin. Their maximum photopolymerization rates (Rpmax) and final unsaturation conversion (Pf) in the cured films at the presence of a 3 wt% photofragmenting initiator were investigated. The results showed that the Pf increased with increasing EB220 content photo-DSC analysis. The data from dynamic mechanical thermal analysis showed that BPAAEP has good miscibility with EB220. Moreover, the crosslink density and Tg of the cured film decreased along with the content of BPAAEP in the blend.