کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1401570 | 1501711 | 2016 | 8 صفحه PDF | دانلود رایگان |

• Diphenyldihdroacridine and its Si and Ge brided analogues were synthesized.
• Corresponding nitroxide radical derivatives were synthesized.
• Their crystal structures were revealed by X-ray crystallographic analysis.
• The physicochemical properties are evaluated by UV–vis, fluorescence, EPR and CV measurements.
• The obtained experimental results were discussed in connection with DFT calculations.
Three dihydroacridine analogues, 2,7-dimethoxy-9,10-dihydro-9,9-diphenylacridine (1-C), 2,8-dimethoxy-10,10-diphenyl-5,10-dihydrophenazasiline (1-Si), and 2,8-dimethoxy-10,10-diphenyl-5,10-dihydrophenazagermine (1-Ge), and corresponding nitroxide radical derivatives, 2,7-dimethoxy-9,10-dihydro-9,9-diphenylacridine-10-oxyl (2-C), 2,8-dimethoxy-10,10-diphenyl-5,10-dihydrophenazasiline-5-oxyl (2-Si), and 2,8-dimethoxy-10,10-diphenyl-5,10-dihydrophenazagermine-5-oxyl (2-Ge) were synthesized in order to study the effect of the Si and Ge bridging atoms on the physicochemical properties of the diaryl nitroxide radical derivatives. These derivatives were stable in non-halogenated solvents and in the solid state. Their structures were crystallographically analyzed and UV–vis, fluorescence, EPR, and cyclic voltammetry measurements were performed to investigate the physicochemical properties of the dihydroacridine analogues and nitroxide radical derivatives.
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Journal: Journal of Molecular Structure - Volume 1106, 15 February 2016, Pages 399–406