کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1401641 1501715 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Reduction of 4-azidonaphthalimide with different phosphine ligands and exploration of their spectroscopic properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Reduction of 4-azidonaphthalimide with different phosphine ligands and exploration of their spectroscopic properties
چکیده انگلیسی


• The reduction of 4-azidonaphthalimide to 4-aminonaphthalimide by using PMe3 ligand.
• 4-Substituted 1,8-naphthalimide iminophosphoranes were successfully synthesized.
• Their optical properties could be tuned by different phosphine ligands.

A convenient, high efficient method for the reduction of 4-azidonaphthalimide to 4-aminonaphthalimide (1) by using PMe3 has been developed. Several 4-substituted 1,8-naphthalimide iminophosphoranes were also successfully synthesized. Their structures were characterized by NMR and MS analyses. The structures of compounds 2 and 3 were also confirmed by single crystal X-ray diffraction analysis. Their optoelectronic properties of these naphthalimides were investigated. The results indicated that their optical properties could be tuned by different phosphine ligands, which make them novel potential organic luminescent materials.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1102, 15 December 2015, Pages 197–202
نویسندگان
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