کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1401908 | 1501725 | 2015 | 11 صفحه PDF | دانلود رایگان |

• Five terminally substituted azobenzene chromophores having azocinnamate as central linkages have been prepared.
• The synthesized liquid crystalline compounds exhibit mesomorphism.
• The effects of morphological modifications on mesophase were studied.
• All the compounds exhibit photoisomerization.
A series of azobenzene-containing mesogens end-capped with cinnamoyl esters were synthesized and investigated its mesogenic and photochemical properties. Terminal substituents of the molecules were changed with various substituents like CN, Cl, H, CH3, and OCH3. Liquid crystalline properties of the synthesized compounds were studied and confirmed using differential scanning calorimetry, polarising optical microscopy. Compounds (4a–4e) exhibited a thermotropic mesomorph behaviour viz., nematic and smectic phases that depends on the terminal substituents. The thermal transition temperatures and the mesophase types are depend on the terminal substituents which are ascribed with the increasing cohesive forces between molecules as the conjugation length increases. These photochromic compounds exhibited strong UV–vis absorption maxima between 330 and 340 nm. Upon irradiation with selective UV light produces the trans–cis isomerization producing new maxima at 450 nm due to cis configuration.
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Journal: Journal of Molecular Structure - Volume 1092, 15 July 2015, Pages 176–186