کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1401981 1501729 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Palladium(II) complex with thiazole containing tridentate ONN donor ligand: Synthesis, X-ray structure and DFT computation
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Palladium(II) complex with thiazole containing tridentate ONN donor ligand: Synthesis, X-ray structure and DFT computation
چکیده انگلیسی


• Palladium(II) complex.
• Thiazole containing ONN donor ligand.
• X-ray and electronic structure.
• Electrochemistry.
• DFT and TDDFT calculation.

New palladium(II) complex with 2-(2-thiazolyl)-4-methylphenol (TAC) having general formula [Pd(TAC)Cl) (1) has been synthesized and characterized. The complex has been characterized by various spectroscopic techniques. Single crystal X-ray structure shows distorted square planar geometry around palladium(II). Cyclic voltammetric studies shows ligand based irreversible oxidation and reduction peaks. The electronic structure, redox properties and electronic excitations in the complex are interpreted by DFT and TDDFT calculations.

Palladium(II) complex with 2-(2-thiazolyl)-4-methylphenol (TAC) having general formula [Pd(TAC)Cl) (1) has been synthesized and characterized by various spectroscopic techniques. Geometry has been confirmed by single crystal X-ray study. Cyclic voltammetric studies shows ligand based irreversible oxidation and reduction peaks. The electronic structure, redox properties and electronic excitations in the complex are interpreted by DFT and TDDFT calculations.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1088, 15 May 2015, Pages 28–33
نویسندگان
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