کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1402120 | 1501737 | 2015 | 5 صفحه PDF | دانلود رایگان |
• Ortho-hydroxy aryl and heterocyclic Schiff bases.
• Tautomeric equilibrium.
• Intramolecular hydrogen bond.
• Pyridoxal derivatives.
The article reports on the synthesis and crystallographic and theoretical studies on various heterocyclic derivatives of ortho-hydroxy Schiff bases. The prevailing of one of the two (enolimine – OH and ketoamine – NH) tautomeric forms has been stated in studied compounds depending on the substitutes in heterocyclic formation, the nitrogen and carbon atoms of the imine group. A specific situation has been shown in (1E)-1-(5-chloro-2-hydroxy-3-nitrophenyl)ethanone oxime compound. The potentials on the proton transfer of the hydrogen bridges in these compounds have been found out. Grounded on the obtained potential curves the influence of the protonation on nitrogen in the pyridoxal derivative of the studied ortho-hydroxy Schiff bases has been analysed. The most efficient method of the impact (by means of various substitutes) on the intramolecular tautomeric equilibrium in ortho-hydroxy Schiff bases has been presented.
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Journal: Journal of Molecular Structure - Volume 1080, 25 January 2015, Pages 52–56