Chemorheological study of the curing kinetics of a phenolic resol resin gelled

The changes in the resin viscosity, conductivity, mass, and enthalpy during curing reactions have been studied to obtain kinetic parameters that allow modeling of the resin behavior throughout its industrial application. In this work, isothermal rheological tests of a phenolic resol resin were performed in order to study its complex viscosity during crosslinking reactions. Samples were prepared by a precuring treatment in a heated plate press to reach gel point of the resin. Rheological analyses of resol resin curing were carried out at five different temperatures (80–100 °C), and the kinetic models of Arrhenius and Kiuna were applied. The resol resin curing presented an activation energy of 72.1 kJ/mol according to the Arrhenius model. The Kiuna model was proposed to fit the non-linear evolution of the resin’s complex viscosity at the highest temperatures. This kinetic model was suitable for predicting the changes in the complex viscosity of the resol resin after its gelation, and the process activation energy obtained for the second order polynomial applied in this model was 88.1 kJ/mol. In addition, the profile for the degree of curing of resol resin was determined from measurements of the material’s elastic modulus.

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