کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1402969 | 1501774 | 2013 | 6 صفحه PDF | دانلود رایگان |
The rearrangements of 1-octyl, 1-decyl and 1-tridecyl intermediates obtained from thermal lead(IV) acetate (LTA) decarboxylation of nonanoic, undecanoic and tetradecanoic acid were investigated experimentally through analysis and distribution of the products. The relationships between 1,5-, 1,6- and possibly existing 1,7-homolytic hydrogen transfer in 1-octyl-radical, as well as successive 1,2-hydride shift in corresponding cation have been computed via Monte-Carlo method. Taking into account that ratios of 1,5-/1,6-homolytic rearrangements in 1-octyl- and 1-tridecyl radical are approximately the same, the simulation shows very low involvement of 1,7-hydrogen rearrangement (1,5-/1,6-/1,7-hydrogen rearrangement = 85:31:1) in 1-octyl radical.
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► Rearrangements products distribution study of the long-chain radicals and cations.
► Monte Carlo simulation of the stabilization processes of 1-octyl radical.
► Ratio of homolitical rearrangements determined by Monte Carlo simulation.
Journal: Journal of Molecular Structure - Volume 1040, 22 May 2013, Pages 19–24