کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1403064 | 1501777 | 2013 | 6 صفحه PDF | دانلود رایگان |
A bi-1,3,4-oxadiazole derivative (BOXDH-T12) showed intramolecular charge transition at concentrations lower than 1 × 10−5 mol/L. The self-assembling behaviors of BOXDH-T12 depended on solvents that it self-assembled into H-aggregates in alcohols and slipped packing aggregates in DMSO. FTIR, 1H NMR and TGA results revealed that strong gelator–gelator hydrogen bonding interaction induced H-aggregation of BOXDH-T12 in alcohols and the interactions between DMSO and BOXDH-T12 molecules caused a slipped stacking. BOXDH-T12 can gel the mixtures of DMSO and ethanol through a cooperative effect of the hydrogen bonding, van der Waals interaction and π–π stacking forces, furthermore, helical ribbons could be observed in DMSO/ethanol due to DMSO molecule interacting. In alcohols, solvophobic/solvophilic effect plays a critical role in gelation behaviors.
FTIR, 1H NMR, WAXD and TGA results suggested that strong gelator–gelator intermolecular hydrogen bonding interaction induced H-aggregation of BOXDH-T12 while the interaction between DMSO and BOXDH-T12 molecules caused the slipped stacking. Adding ethanol into DMSO solution of BOXDH-T12, morphologies changed from microparticles to helix.Figure optionsDownload as PowerPoint slideHighlights
► H-aggregate and slipped aggregate of BOXDH-T12 could be obtained by controlling hydrogen bonding formation.
► Helical fibers of BOXDH-T12 could be obtained by adding ethanol into DMSO solution.
► It was demonstrated that the solvophobic/solvophilic effect played a critical role in alcohol gels.
Journal: Journal of Molecular Structure - Volume 1037, 10 April 2013, Pages 130–135