کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1403162 1501779 2013 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solid and solution evidences on the temperature effect of N-chelated zinc phthalates
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Solid and solution evidences on the temperature effect of N-chelated zinc phthalates
چکیده انگلیسی

Progressive reactions of zinc(II) phthalate in the presence of 2,2-bipyridine result in the isolations of three complexes, [Zn(phth)(bpy)(H2O)]2·2H2O (1), [Zn(phth)(bpy)(H2O)]2 (2) and {[Zn(phth)(bpy)(H2O)][Zn(phth)(bpy)]·H2O}n (3) (bpy = 2,2-bipyridine). Heating the reaction mixture reduces the coordination numbers from distorted octahedron, trigonal–bipyramid to tetrahedron configurations. The metal configurations of the isolated complexes depend on the reaction temperature. Detailed comparisons in solid and solution NMR spectra reveal that dimers 1 and 2 show no decomposition in solution and retain their coordinated structures in solid. Obvious downfield shifts (Δδ = 3.19 and 2.31 ppm) of carboxy groups in 2 are observed compared with those of dihydrates 1 in solid and solution respectively, which are consistent with the bond strengths of their structures.


► Increase of reaction temperature decreases the coordination numbers in zinc phthalate.
► The configurations change from octahedron, trigonal-bipyramid to tetrahedron.
► The two dimers retain their structures in solution based on solid and solution NMR measurements.
► Obvious downfield shifts of carboxy groups in NMR are consistent with the bond strengths of their structures.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1035, 13 March 2013, Pages 198–202
نویسندگان
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