کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1403490 | 984828 | 2007 | 12 صفحه PDF | دانلود رایگان |

Polyester acrylate inorganic/organic hybrids were prepared using a sol–gel precursor, coupling agent, and reactive diluent. The hybrids were cured via a UV-free radical initiator. Design of experiments (DOE) was utilized to investigate reaction kinetics and complex variable interactions. The effects of the silicate groups on the free radical photo-curing reaction kinetics were investigated utilizing a time-resolved Fourier transform infrared (FT–IR) spectroscopy and a differential scanning calorimeter equipped with a photocalorimetric accessory (photo-DSC). Microgel and inorganic network formation during the UV-initiated free radical crosslinking reactions was suggested to describe the complex gel-point behavior. It was proposed that the formation of the inorganic silicate groups retarded the organic crosslinking reactions. The UV-cured inorganic/organic hybrid films exhibited more homogeneous film morphology compared to the organic counterparts. In the hybrid films, a core–shell like inorganic/organic particle morphology was observed. The UV-crosslinked organic phase forms the core, whereas, the inorganic silicate forms the surrounding shell.
Journal: European Polymer Journal - Volume 43, Issue 8, August 2007, Pages 3325–3336