کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1403673 984838 2007 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Swelling behaviour of crosslinked hydrogels based on (2-hydroxyethyl methacrylate) with a zwitterionic comonomer (1-3-sulfopropyl-2-vinyl-pyridinium-betaine)
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Swelling behaviour of crosslinked hydrogels based on (2-hydroxyethyl methacrylate) with a zwitterionic comonomer (1-3-sulfopropyl-2-vinyl-pyridinium-betaine)
چکیده انگلیسی

Copolymeric hydrogels were prepared by the chemically initiated free radical copolymerization in aqueous solution of mixtures of [1-(3-sulfopropyl)-2-vinyl-pyridinium-betaine] (SPV) and (2-hydroxyethyl methacrylate) (HEMA) in the presence of a crosslinking agent N,N′-methylene-bis-acrylamide (MBA). The hydrogels were swollen to equilibrium in water and aqueous KSCN at 298 K and their swelling behaviour has been investigated using gravimetric measurements. The effects of the concentration of KSCN and the mole fraction of SPV in the feed (Fs) have been noted and discussed. The main findings are:(a) In water, the water content (W1) of copolymeric hydrogels is insensitive to SPV content at Fs ⩾ 0.45. In contrast, W1 decreases sharply with decreasing Fs within the range of 0 < Fs < 0.45. (b) In aq. KSCN, the degree of total swelling (W) exceeds the value in pure water, the enhancement in swelling being most marked at low values of [KSCN]. The content of water within the hydrogel increases with KSCN concentration in the swelling medium for low values of [KSCN], but thereafter falls with further increase in salt concentration. In contrast, the salt content within the swollen hydrogel displays a continuous increase with increasing [KSCN]. All these results of item (b) are for copolymeric hydrogels within the full range of Fs (0 < Fs < 1). (c) at a fixed aq. KSCN concentration, both W and W1 increase sharply with increasing Fs over the entire range of copolymer composition.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: European Polymer Journal - Volume 43, Issue 3, March 2007, Pages 915–927
نویسندگان
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