کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1404463 1501910 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel three-dimensional CuII–MoIV bimetallic complex: Synthesis, crystal structure, and magnetic properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
A novel three-dimensional CuII–MoIV bimetallic complex: Synthesis, crystal structure, and magnetic properties
چکیده انگلیسی

The reaction between K4[MoIV(CN)8]·2H2O and [Cu(L)](ClO4)2 (L=3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane) gives a novel three-dimensional cyano-bridged coordination compound [Cu(L)]2[Mo(CN)8]·2.5H2O (1). The thermal and magnetic behaviors of compound 1 have been investigated. X-ray single-crystal structure determinations reveal that the MoIV centers in 1 adopt a distorted square antiprism geometry, while the CuII centers in 1 adopt an elongated octahedral geometry. Each MoIV coordinated via four cyano groups to four CuII. Variable-temperature magnetic susceptibility measurements reveal that there is negligible magnetic interaction between the CuII centers in compound 1.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 826, Issues 2–3, 29 January 2007, Pages 165–169
نویسندگان
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