کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1404530 | 1501914 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
New 3-D supramolecular networks formed via hydrogen bonding and Ï-Ï stacking interactions: Synthesis, characterization and crystal structures
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: New 3-D supramolecular networks formed via hydrogen bonding and Ï-Ï stacking interactions: Synthesis, characterization and crystal structures New 3-D supramolecular networks formed via hydrogen bonding and Ï-Ï stacking interactions: Synthesis, characterization and crystal structures](/preview/png/1404530.png)
چکیده انگلیسی
Two new 3-D supramolecular networks, {[Cd2(dap)2(tp)2(H2O)2] · 2H2O}n (1) and {[Cu3(tp)2(dpq)2(OH)2]}n (2) (tp, terephthalate; dap, 5,6-diamino-1,10-phenanthroline; dpq, dipyrido[3,2-d:2â²,3â²-f]quinoxaline), have been synthesized and structurally characterized by X-ray diffraction. Single-crystal X-ray analyses show that complex 1 is constructed by CdII and mixed ligands of daps and tps to form a 1-D polymer chain. In complex 2, a tetra-coordinated CuII and two penta-coordinated CuII are linked by two bridging hydroxyl oxygen atoms to form a Cu3(OH)2(dpq)2 unit, which is a noteworthy feature in the framework, and such units are connected through tp to form a 2-D lamellar polymer. Moreover, complexes 1 and 2 are further extended into 3-D supramolecular networks by H-bonding and Ï-Ï stacking interactions, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 798, Issues 1â3, 23 October 2006, Pages 34-39
Journal: Journal of Molecular Structure - Volume 798, Issues 1â3, 23 October 2006, Pages 34-39
نویسندگان
Xiu-Li Wang, Hong-Yan Lin, Tong-Liang Hu, Jin-Lei Tian, Xian-He Bu,