کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1404860 | 1501724 | 2015 | 6 صفحه PDF | دانلود رایگان |
• TQPP materials with thermal stability up to 370 °C were synthesized.
• TQPP and TQPP-[CH3]4 show interplanar stacking distances of 3.4 Å using X-ray crystallography.
• OTFT field-effect mobilities of 10−3 cm2/V−1 s−1 for TQPP and 10−5 cm2/V−1 s−1TQPP-[CH3]4.
• Modeling confirms higher electronic coupling constants for TQPP than TQPP-[CH3]4.
Two p-type semiconducting azapyrenoacene materials, quinoxalino[2′,3′:9,10]phenanthro[4,5-abc]phenazine (TQPP) and 6,7,15,16-tetramethylquinoxalino[2′,3′:9,10]phenanthro[4,5-abc]phenazine (TQPP-[CH3]4), were characterized and were found to display high thermal stability and planar molecular geometry as revealed by single-crystal X-ray analysis. In bottom-gate p-channel organic thin-film transistors, field-effect mobilities of 2.5 × 10−3 cm2/V s and 7.5 × 10−5 cm2/V s were measured in ambient air for TQPP and TQPP-[CH3]4, respectively. Computational results of reorganization energies and electronic couplings indicate larger inter and intra-columnar couplings for TQPP-[CH3]4 in comparison to TQPP and predict the suitability of both semiconductors for hole as well as electron transporters.
TQPP (X = H): μ = 2.5 × 10−3 cm2/V s. TQPP (X = CH3): μ = 7 × 10−5 cm2/V s.Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Structure - Volume 1093, 5 August 2015, Pages 144–149