کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1405098 | 1501747 | 2014 | 5 صفحه PDF | دانلود رایگان |
• A new heterometallic complex with 1,3,5-benzenetricarboxyl acid has been synthesized.
• The structure of the complex is determined by X-ray study.
• The complex shows a 3D structure with (3,4,5)-connected net topology.
• The coordination polymer is characterized by FT-IR, luminescence and TGA techniques.
A novel three-dimensional Ag(I)–Pb(II) heteronuclear coordination polymer, namely [Ag2Pb2(BTC)2(H2O)2]n (1), where H3BTC = 1,3,5-benzenetricarboxyl acid, has been hydrothermally synthesized and structurally characterized by elemental analysis(EA), infrared spectroscopy(IR) and single crystal X-ray diffraction. The BTC3− ligand exhibits an interesting coordination mode to form a three-dimensional (3D) framework with a novel hexa-nodal (3,4,5)-connected net topology. The thermal stability and solid state fluorescence of 1 have also been investigated.
Journal: Journal of Molecular Structure - Volume 1070, 24 July 2014, Pages 75–79