کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1405533 | 1501749 | 2014 | 13 صفحه PDF | دانلود رایگان |
• Structural elucidation of carbene proligands.
• Weak non-covalent interactions.
• Cooperative anion⋯π and π–π interactions.
• Hirshfeld surface analyses.
• Fingerprint plots.
The cooperative effect of weak non-covalent forces between anions and electron deficient aromatics by π⋯π stacking of a series of carbene proligands (1–3) have been thoroughly explored by crystallographic studies. Structural analysis revealed that the anion⋯π and π⋯π interactions along with intermolecular hydrogen bonding mutually cooperate to facilitate the assembling of the supramolecular framework. The π⋯π and corresponding anion⋯π interactions have been investigated in the title carbene proligands despite their association with counter ions. The presence of the anion in the vicinity of the π-system leads to the formation of anion⋯π/π⋯π/π⋯anion network for an inductive stabilization of the assemblies. To assess the dimensionality of the supramolecular framework consolidated by cooperative anion⋯π/π⋯π interactions and hydrogen bonding, different substituent effects in the carbene backbone have been considered to tune these interactions. These facts show that the supramolecular framework based on these cooperative weak forces may be robust enough for application in molecular recognition. The investigation of close intermolecular interactions between the molecules via Hirshfeld surface analyses is presented in order to reveal subtle differences and similarities in the crystal structures. The decomposition of the fingerprint plot area provides a percentage of each intermolecular interaction, allowing for a quantified analysis of close contacts within each crystal.
The presence of the hexafluorophosphate anion in the vicinity of the π-system of three carbene proligands leads to the formation of anion⋯π/π⋯π/π⋯anion network for an inductive stabilization of the supramolecular assemblies.Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Structure - Volume 1068, 25 June 2014, Pages 58–70