کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1405775 | 1501758 | 2014 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Structural characterization of new 2-aryl-5-phenyl-1,3,4-oxadiazin-6-ones and their N-aroylhydrazone precursors Structural characterization of new 2-aryl-5-phenyl-1,3,4-oxadiazin-6-ones and their N-aroylhydrazone precursors](/preview/png/1405775.png)
• New oxadiazinones by intramolecular cyclization of corresponding N-aroylhydrazones.
• Electronic properties of oxadiazinones are mainly influenced by the 2-aryl substituent.
• Isolation of Z,anti isomer of N-aroylhydrazones.
• Strong intermolecular interactions in the solid state revealed for N-aroylhydrazones.
A series of novel 2,5-disubstituted 1,3,4-oxadiazin-6-ones and their N-aroylhydrazone precursors were synthesized and characterized by NMR and UV–Vis spectroscopy. The electronic properties of 2-aryl-5-phenyl-1,3,4-oxadiazin-6-ones are mainly dependent on the 2-aryl substituent and their absorption maxima exhibit a red shift in dichloromethane. Single crystal X-ray diffraction on four acylhydrazones indicated the isolation of isomer with Z configuration of the CN double bond. Intermolecular interactions through strong H-bonding and CH⋯π contacts serve to link the molecules into a three-dimensional supramolecular network.
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Journal: Journal of Molecular Structure - Volume 1058, 24 January 2014, Pages 106–113