کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1406098 | 1501834 | 2010 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Isolation of a new bromocadmate(II) anion stabilized by second sphere coordination: [Co(NH3)6]2[Cd3Br10(H2O)2]Br2·2H2O
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Utility of second sphere interactions for the isolation of a new polycadmate(II) anion is demonstrated through the synthesis of [Co(NH3)6]2[Cd3Br10(H2O)2]Br2·2H2O. The anion is stabilized through the unison of large number of N-Hâ¯Br second sphere interactions. The packing analysis delineates that the polycadmate(II) anion is not discrete but form polymeric ribbons of repeated formula, [Cd3Br10(H2O)2]4â that run along a axis of the unit cell. The complex cations, bromide ions and lattice water molecules are between and in the offsets between the corrugated anion ribbons. The study also advances the cooperative role of second sphere interactions amid electrostatic forces that stabilize the crystal lattice.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 980, Issues 1â3, 10 September 2010, Pages 261-266
Journal: Journal of Molecular Structure - Volume 980, Issues 1â3, 10 September 2010, Pages 261-266
نویسندگان
Raj Pal Sharma, Rajni Sharma, Ajnesh Singh, Anju Saini, Alexander I. Gubanov, Anton I. Smolentsev, Paloth Venugopalan,