کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1406414 1501853 2009 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrogen bond-directed co-crystals of (±)-1,1′-binaphthalene-2,2′-diol with aromatic diimines: Structures and selectivity
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Hydrogen bond-directed co-crystals of (±)-1,1′-binaphthalene-2,2′-diol with aromatic diimines: Structures and selectivity
چکیده انگلیسی
As a result of mutual recognition, 1,1′-binaphthalene-2,2′-diol(binol) (1) and various aromatic diimines including 2,9-dimethyl-1,10-phenanthroline (2), 4,5-diazafluoren-9-one (3), 4,4′-dimethyl-2,2′-bipyridine (4), 4,4′-bipyridine (5), and 5-nitro-1,10-phenanthroline (6) formed well-defined co-crystals 2a, 3a, 4a, 5a and 6a, respectively. In 2a, 3a, 5a and 6a, the components form discrete aggregates, whereas in 4a, the components form infinite one-dimensional arrays. The crystal structures of these co-crystals are all stabilized by O-H···O and O-H···N hydrogen bonds as well as C-H···π and π···π interactions. Remarkably, a preferential co-crystal of 1,10-phenanthroline-5,6-dione (7) over 1,10-phenanthroline (8) and other diimines with binol is established through competitive crystallization and guest-exchange experiments.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 937, Issues 1–3, 26 November 2009, Pages 107-115
نویسندگان
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