کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1406856 | 1501876 | 2008 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Ligand effect on the growth reaction of copper(II) dicyanamide complexes: Syntheses, characterization and X-ray single crystal structure analyses of [CuL{N(CN)2}2]n and [CuL′{N(CN)2}2]2 [L = 2-(aminoethyl)pyridine and L′ = 2-(aminomethyl)pyridine]
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Ligand effect on the growth reaction of copper(II) dicyanamide complexes: Syntheses, characterization and X-ray single crystal structure analyses of [CuL{N(CN)2}2]n and [CuL′{N(CN)2}2]2 [L = 2-(aminoethyl)pyridine and L′ = 2-(aminomethyl)pyridine] Ligand effect on the growth reaction of copper(II) dicyanamide complexes: Syntheses, characterization and X-ray single crystal structure analyses of [CuL{N(CN)2}2]n and [CuL′{N(CN)2}2]2 [L = 2-(aminoethyl)pyridine and L′ = 2-(aminomethyl)pyridine]](/preview/png/1406856.png)
چکیده انگلیسی
The ligands 2-(aminoethyl)pyridine (L) and 2-(aminomethyl)pyridine (L′) have been chosen to study the role of the organic co-ligands on the geometry of Cu(II)-dicyanamide system. On complexation with L polymeric species is obtained, whereas, the growth reaction is observed to be terminated after dimerization on complexation with L′. The polymeric species, [CuL{N(CN)2}2]n, and the dimeric species, [CuL′{N(CN)2}2]2, have been characterized by routine physicochemical techniques and by single crystal X-ray diffraction and their formation has been rationalized. Two types of coordination modes of dicyanamide, monodentate and μ1,5 are observed in both the complexes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 888, Issues 1–3, 15 October 2008, Pages 62–69
Journal: Journal of Molecular Structure - Volume 888, Issues 1–3, 15 October 2008, Pages 62–69
نویسندگان
Tanmay Chattopadhyay, Arpita Banerjee, Kazi Sabnam Banu, Nirmalya Podder, Madhuparna Mukherjee, Manami Ghosh, Eringathodi Suresh, Debasis Das,