کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1407314 1501880 2008 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Patterns of cross peaks in 2D synchronous spectrum generated by using orthogonal sample design scheme
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Patterns of cross peaks in 2D synchronous spectrum generated by using orthogonal sample design scheme
چکیده انگلیسی

A computer simulation is applied on a model chemical system to study patterns of cross peaks in 2D synchronous spectrum generated by using orthogonal sample design scheme. Variations on different spectral parameters, such as peak position, bandwidth, and absorptivity, caused by intermolecular interactions result in rich and complex behavior in 2D synchronous spectrum. Subtle spectral variations that are hard to be observed in 1D spectra can be clear observed in 2D synchronous spectra. The results suggest that the cross peaks in 2D synchronous spectrum generated by using orthogonal sample design (OSD) can act as a resolution enhancement tool that can differentiate highly overlapping bands.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volumes 883–884, 30 July 2008, Pages 129–136
نویسندگان
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