کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1407684 | 1501695 | 2016 | 7 صفحه PDF | دانلود رایگان |
• Cruciform molecular systems were synthesized and structurally characterized.
• The orientation of the analytes on a gold colloid was inferred from a SERS study.
• The metal surface interaction was driven by the heteroatoms in thiophene and furan.
• The plane of the anthracene fragment remained parallel to the gold surface.
• Theoretical calculations provided a good representation of the experimental data.
The 9,10-di(thiophen-2-yl)anthracene (TAT), 9,10-di(furan-2-yl)anthracene (FAF) and 2-[(10-(thiophen-2-yl)anthracen-9-yl)]furan (TAF) cruciform molecular systems were synthesized using one-step coupling reactions and structurally characterized via Raman, infrared, 1H NMR, 13C NMR and mass spectroscopies. The orientation of the analytes on a gold colloidal surface was inferred from a surface-enhanced Raman scattering (SERS) study. The metal surface interaction was driven by the S and O atoms of the thiophene and furan α-substituents, and the plane of the anthracene fragment remained parallel to the surface. Theoretical calculations based on a simplified molecular model for the analyte-surface interaction provide a good representation of the experimental data.
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Journal: Journal of Molecular Structure - Volume 1122, 15 October 2016, Pages 198–204