کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1407827 | 1501896 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Copper and cobalt coordination polymers based on isophthalate as bridging ligands and imidazole as capping ligands: Syntheses, crystal structures, spectroscopic characterization
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Two novel coordination polymers, {[Cu(ip)(Him)2(DMF)]·H2O} (1) and Co(ip)(Him)2 (2), (ip = isophthalate, Him = imidazole) were prepared under hydrothermal conditions and their structures were determined by single-crystal X-ray diffraction. X-ray structural analysis reveals that 1-D zigzag metal-organic chains are connected to form a 3-D supramolecular framework in compounds 1 and 2 by hydrogen-bonding and π–π interaction or other intermolecular contacts. Infrared, UV–vis, and elemental analysis were performed to characterize the two compounds. The result of magnetic determination for compound 2 shows there exist antiferromagnetic interaction between magnetic centers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 842, Issues 1–3, 15 October 2007, Pages 125–131
Journal: Journal of Molecular Structure - Volume 842, Issues 1–3, 15 October 2007, Pages 125–131
نویسندگان
Jiang-Feng Song, Yan Chen, Zhi-Gang Li, Rui-Sha Zhou, Xiao-Yu Xu, Ji-Qing Xu,