کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1407860 | 1501923 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
pH-controlled assembly of two polyoxovanadates based on [V16O38(Cl)]8− and [V15O36(Cl)]6− building blocks
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: pH-controlled assembly of two polyoxovanadates based on [V16O38(Cl)]8− and [V15O36(Cl)]6− building blocks pH-controlled assembly of two polyoxovanadates based on [V16O38(Cl)]8− and [V15O36(Cl)]6− building blocks](/preview/png/1407860.png)
چکیده انگلیسی
Two new inorganic–organic hybrid polyoxovanadates, [Cu(2,2′-bipy)3]2[H4V16O38(Cl)]·4H2O 1 and [Cu(2,2′-bipy)3]3[V15O36(Cl)]·3H2O 2 (2,2′-bipy=2,2′-bipyridine), have been prepared under the hydrothermal conditions and structurally characterized by elemental analysis, IR spectra, EPR spectra, TG analyses and single-crystal X-ray diffraction. Compounds 1 and 2 are based on [V16O38(Cl)]8− and [V15O36(Cl)]6− building block, respectively. They were synthesized under the same reaction condition but in different pH range, which shows that the pH value of the reaction plays a key role in the structural control of self-assemble process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 788, Issues 1–3, 8 May 2006, Pages 200–205
Journal: Journal of Molecular Structure - Volume 788, Issues 1–3, 8 May 2006, Pages 200–205
نویسندگان
Baoxia Dong, Jun Peng, Yanhui Chen, Yumei Kong, Aixiang Tian, Hongsheng Liu, Jingquan Sha,