کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1407960 | 1501924 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and crystal structure of a new charge transfer salt [NBu4]6H[Fe(C5H5)2][PMoVMo11O40]2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and crystal structure of a new charge transfer salt [NBu4]6H[Fe(C5H5)2][PMoVMo11O40]2 Synthesis and crystal structure of a new charge transfer salt [NBu4]6H[Fe(C5H5)2][PMoVMo11O40]2](/preview/png/1407960.png)
چکیده انگلیسی
A new charge transfer salt, [NBu4]6H[Fe(C5H5)2][PMo12O40]2, based on Fe(C5H5)2 (ferrocene) and Keggin-type anion [PMo12O40]3â was electrochemically synthesized and its structure was determined by single-crystal X-ray diffraction. Monoclinic, C2/c, M=4068.12, a=50.383(18)Â Ã
, b=14.113(5)Â Ã
, c=26.554(10)Â Ã
, β=115.318°, V=17068(11) Ã
3, Z=6, R1=0.0759, wR2=0.1744 (I>2Ï). The layers of the organic donor and inorganic acceptor in solid state are alternatively arranged in (001) plates and each [Fe(C5H5)2]+ is surrounded by four Keggin-type anions. There are weak interactions between organic and inorganic layers. ESR spectrum at 110Â K displays distinct ferrocenyl cation [Fe(C5H5)2]+ and Mo5+ signals, the anion [PMo12O40]3â is reduced by one electron. The CV properties of the complex were also discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 787, Issues 1â3, 17 April 2006, Pages 101-105
Journal: Journal of Molecular Structure - Volume 787, Issues 1â3, 17 April 2006, Pages 101-105
نویسندگان
Xuemei Liu, Ganglin Xue, Huaiming Hu, Quanchang Gao, Feng Fu, Jiwu Wang,