کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1407985 | 1501717 | 2015 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Organic carboxylate ligands tuned structural variations of two new Cd(II) coordination polymers: From 2D layer to 3D framework
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Two new Cd(II) coordination polymers, namely [Cd(4,4â²-sdb) (biimpy)]n·1.5n(H2O) (1) and [Cd2(Htci)2(biimpy)2]n (2) (4,4â²-H2sdb = 4,4â²-sulfonyldibenzoate, H3tci = tri(2-carboxyethyl)isocyanurate and biimpy = 2,6-bis(1-imdazoly)pyridine), have been synthesized by the hydrothermal reactions of Cd(NO3)2 and the mixed ligands of 4,4â²-H2sdb and biimpy or H3tci and biimpy. Single crystal X-ray structural analyses reveal that compound 1 features a 2D layered structure with 3-connected topology, and compound 2 features a 3D framework with 6-connected 6T8 topology. In addition, the thermal stabilities and luminescent properties of compounds 1 and 2 were also investigated.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1100, 15 November 2015, Pages 1-5
Journal: Journal of Molecular Structure - Volume 1100, 15 November 2015, Pages 1-5
نویسندگان
Chang-Wei Lv, Jing Li, Yan-Wu Liu, Xia Li, Zhi Yuan,