Synthesis, characterization and X-ray crystal structures of Vanadium(IV), Cobalt(III), Copper(II) and Zinc(II) complexes derived from an asymmetric bidentate Schiff-base ligand at ambient temperature

• A bidentate Schiff base ligand (HL) was synthesized and characterized by different spectroscopic techniques.
• VOL2, CoL3, CuL2 and ZnL2 complexes were synthesized with the bidentate Schiff base ligand.
• All the complexes were characterized by elemental analysis, FT-IR and single crystal X-ray diffraction technique.
• ZnL2 complex was investigated by NMR techniques.

An asymmetric bidentate Schiff-base ligand (HL: 2-((allylimino)methyl)phenol) was prepared from reaction of salicylaldehyde and Allylamine. Vanadium(IV), Cobalt(III), Copper(II) and Zinc(II) complexes, VOL2, CoL3, CuL2 and ZnL2 were synthesized from the reaction of VO(acac)2, CoCl2·6H2O, CuCl2·2H2O and Zn(NO3)2·6H2O with the bidentate Schiff base ligand (HL: 2-allyliminomethyl-phenol) in methanol at ambient temperature. The ligand and its metal complexes were characterized by elemental analysis (CHN), FT-IR spectroscopy. In addition, 1H and 13C NMR techniques were employed for characterization of the ligand (HL) and diamagnetic complex ZnL2. The molecular structures of all complexes were determined by single crystal X-ray diffraction technique. In the ZnL2 and CuL2 complexes, the metal ion is coordinated by two nitrogen and two oxygen atoms from two Schiff base ligands in an approximately square planar trans-[MN2O2] coordination geometry. In the Vanadium(IV) complex, VOL2, the vanadium center in this structure has a distorted tetragonal pyramidal N2O3 coordination sphere and for Cobalt(III) complex, CoL3, the CoIII ion is six coordinated by three bidentate Schiff base ligands in a distorted octahedral environment.