کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1408536 | 1501930 | 2006 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: High-resolution infrared study of the ν1 and ν3 bands, and the equilibrium structure of AsD3 High-resolution infrared study of the ν1 and ν3 bands, and the equilibrium structure of AsD3](/preview/png/1408536.png)
The infrared spectrum of the AsD3 molecule has been measured in the region of the stretching fundamental bands on a Fourier transform spectrometer with a resolution of 0.0027 cm−1 and analyzed for the first time. More than 3300 normally allowed and in addition more than 900 forbidden, but perturbation-allowed transitions with Jmaxupper=28 have been assigned to the bands ν1 and ν3. An effective Hamiltonian was used which takes into account the resonance interactions between the states (1000) and (0010). A set of 50 (26 diagonal and 24 resonance) refined spectroscopic parameters was obtained from the fit which reproduces the 1229 initial ‘experimental’ upper state ro-vibrational energies with an rms deviation of 0.00024 cm−1. The transition moment ratio |μ1:μ3| was determined to be 1.2±0.05, and the intensity perturbation μ1ξ13yμ3 found to be negative. The equilibrium values of the bond length rAs–De=1.51130(11)Å and interbond angle αD–As–De=92.0775(40)˚ were determined from the values of the rotational parameters of the ground state and the four fundamental bands.
Journal: Journal of Molecular Structure - Volumes 780–781, 3 January 2006, Pages 115–123