کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1408556 1501930 2006 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Internal rotation, quadrupole coupling and structure of (CH3)3SiI studied by microwave spectroscopy and ab-initio calculations
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Internal rotation, quadrupole coupling and structure of (CH3)3SiI studied by microwave spectroscopy and ab-initio calculations
چکیده انگلیسی
The microwave spectrum of (CH3)3SiI and its isotopic species (CH3)329SiI, (CH3)330SiI, and (13CH3)(CH3)2SiI has been studied using a pulsed molecular beam Fourier transform microwave spectrometer in the frequency range of 3-26.5 GHz. The barrier to internal rotation, the iodine quadrupole coupling and the molecular structure were determined. Ab initio calculations were compared with the experimental results.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volumes 780–781, 3 January 2006, Pages 295-299
نویسندگان
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