کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1408959 1501785 2012 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Novel decavanadate cluster complexes [H2V10O28][LH]4·nH2O (L = Imidazole, n = 2 or 2-methylimidazole, n = 0): Preparation, characterization and genotoxic studies
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Novel decavanadate cluster complexes [H2V10O28][LH]4·nH2O (L = Imidazole, n = 2 or 2-methylimidazole, n = 0): Preparation, characterization and genotoxic studies
چکیده انگلیسی

The title complexes were obtained from the reaction of VOSO4 with imidazole or 2-methyl imidazole in presence of adipic acid/iminodiacetic acid. X-ray crystallographic investigations on [H2V10O28](2-MeImzH)4 (2) revealed a strong interaction between decavanadate anion and the protonated ligand moieties as counter cations to stabilize the crystal motif resulting in a high symmetry 2D sheet network. The cyclic voltammetry of (2) suggested formation of a quasi-reversible redox (VV/IV) couple in the solution. The genotoxic studies employing single cell gel electrophoresis (comet assay) confirmed the non-toxic nature of the compounds.


► The present work describes synthesis and characterization of novel decavanadate complexes.
► The chemistry of guest [H2V10O28]4− anion and host [LH]+ (L = imidazole or 2-methyl imidazole) cations has been developed.
► X-ray crystallographic studies support a regular 2D stacking via H-bonding.
► The CV of the complex (2) has been discussed.
► The genotoxic properties were also assessed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1029, 12 December 2012, Pages 86–91
نویسندگان
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