کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1409344 | 1501751 | 2014 | 15 صفحه PDF | دانلود رایگان |
• Eight organic acid–base adducts with 3D structure have been prepared and structurally characterized.
• The classical hydrogen bonds in the eight supramolecules containing the OH⋯bzim synthons have been discussed.
• The secondary interactions in the solid-state packing of the final structure have also been discussed.
Eight crystalline organic acid–base adducts derived from alkane bridged bis(N-benzimidazole) and organic acids (2,4,6-trinitrophenol, p-nitrobenzoic acid, m-nitrobenzoic acid, 3,5-dinitrobenzoic acid, 5-sulfosalicylic acid and oxalic acid) were prepared and characterized by X-ray diffraction analysis, IR, mp, and elemental analysis. Of the eight compounds five are organic salts (1, 4, 6, 7 and 8) and the other three (2, 3, and 5) are cocrystals. In all of the adducts except 1 and 8, the ratio of the acid and the base is 2:1. All eight supramolecular assemblies involve extensive intermolecular classical hydrogen bonds as well as other noncovalent interactions. The role of weak and strong noncovalent interactions in the crystal packing is ascertained. These weak interactions combined, all the complexes displayed 3D framework structure. The results presented herein indicate that the strength and directionality of the classical N+–H⋯O−, O–H⋯O, and O–H⋯N hydrogen bonds (ionic or neutral) and other nonbonding associations between acids and ditopic benzimidazoles are sufficient to bring about the formation of cocrystals or organic salts.
Journal: Journal of Molecular Structure - Volumes 1065–1066, 22 May 2014, Pages 120–134