Optical, thermal and dielectric studies in linear hydrogen bonded liquid crystal homologous series

A novel series of hydrogen bonded liquid crystals (HBLC) have been isolated with hydrogen bond forming between fluoro benzoic acid and various alkyloxy benzoic acids respectively. Phase diagram is constructed from the transition temperatures obtained by Differential Scanning Calorimetry (DSC) and Polarizing Optical Microscopic (POM) studies. A new Smectic ordering which is referred as Smectic R is characterized which exhibits a ribbon like phase. Declinations are observed on these ribbons manifesting the presence of the helicoidal structure. Another interesting feature is the observation of optical shuttering action in some of the complexes with the application of external stimulus in the entire thermal range of Nematic phase. Further this phenomenon is reversible in the sense that when the applied stimulus is withdrawn original texture of Nematic is restored. Unwinding of the helix coupled with molecular dipolar reorientation with the application of external field is supposed to be the major reasons for the observed phenomenon.

► A novel HBLC homologous series has been synthesized and characterized.
► A new ribbon texture is characterized.
► Optical shuttering action has been experimentally analyzed in three complexes.
► FlBA + 11BAO exhibit an anomalous dielectric relaxation behavior.
► An interesting observations is the detection of odd–even effect.