کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1409415 1501823 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Crystalline forms of 1,3,5-benzene-tri(pyridinyl)carboxamides: Isolated site hydrates as polymorphs and solvates
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Crystalline forms of 1,3,5-benzene-tri(pyridinyl)carboxamides: Isolated site hydrates as polymorphs and solvates
چکیده انگلیسی

The crystallization of 3-pyridyl (1) and 4-pyridyl (2) analogues of the title compound results in different crystalline hydrates and polymorphs and their crystal structures reveal that 1 and 2 exhibit conformational isomerism. The molecule 1 forms three crystalline forms from MeOH solution depending on concentration of the solution. Among these three forms, two are polymorphic monohydrates. However, the crystallization of 2 was found to be dependent on the solvent of crystallization and resulted in new crystalline form from DMF as a dihydrate. The hydrates of both 1 and 2 can be classified as isolated site hydrates. In these crystal structures, water molecules found to exhibit three types of coordination environments with regard to hydrogen bonds.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 991, Issues 1–3, 5 April 2011, Pages 97–102
نویسندگان
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