کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1409725 | 1501829 | 2011 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation, spectroscopic characterization and crystal structures of ferrocenylalkanediols and derived acetates
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
(meso,dl)-3-(Ferrocenylmethyl)pentane-2,4-diol (3) was synthesized by reduction of 3-(ferrocenylmethyl)pentane-2,4-dione (2) with LiAlH4 in a good yield and corresponding monoacetate 4 and diacetate 5 were prepared. Newly prepared compounds are characterized by elemental analysis, IR and NMR spectroscopy and will be used as a substrate or standards for lipase mediated desymmetrization. The structures of 3-(ferrocenylmethyl)pentane-2,4-diol (3) and 2-(ferrocenylmethyl)propane-1,3-diol diacetate (8), which is derived from prochiral 2-(ferrocenylmethyl)propane-1,2-diol (6), were determined by X-ray crystal structure analysis. The conformation of the cyclopentadienyl rings is eclipsed in 3 and almost halfway between eclipsed and staggered in 8. One OâHâ¯O hydrogen bond links the molecules of diol 3 into chains, while one weak CâHâ¯Ï interaction self-assembles the molecules of diacetate 8 into dimers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 985, Issues 2â3, 31 January 2011, Pages 413-418
Journal: Journal of Molecular Structure - Volume 985, Issues 2â3, 31 January 2011, Pages 413-418
نویسندگان
Jasmina LapiÄ, Josipa BiliÄ, Mario Cetina, Senka DjakoviÄ, Vladimir RapiÄ,