کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1410156 | 1501850 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, crystal structures and characterization of DyIII-containing enantiomeric pair
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
As a result of the reaction between Dy(dbm)3·2H2O and chiral ligands LS,S(+)-4,5-pinene bipyridine or LR,R(â)-4,5-pinene bipyridine, a novel DyIII-based enantiomeric pair, Dy(dbm)3LS,S and Dy(dbm)3LR,R, has been obtained and characterized by X-ray single crystal determination and spectroscopic methods. The crystal structure analysis of 1 and 2 reveals that they crystallize in chiral space group P21 of monoclinic system. The central DyIII ion is eight-coordinated with six oxygen atoms of three β-diketonate anions and two nitrogen atoms of chiral pinene bipyridine, forming a coordination polyhedron best described as the distorted square antiprism. The CD spectra reflect that complexes 1 and 2 are enantiomers. Thermogravimetric analysis results indicate that 1 and 2 are thermally stable up to 249 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 964, Issues 1â3, 14 February 2010, Pages 63-66
Journal: Journal of Molecular Structure - Volume 964, Issues 1â3, 14 February 2010, Pages 63-66
نویسندگان
Xi-Li Li, Lai-Fu He, Shao-Ming Fang, Hong-Ping Xiao,